778621
2,3,4,6-Tetra-O-pivaloyl-α-D-glucopyranosyl bromide
≥90% (TLC)
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About This Item
Empirical Formula (Hill Notation):
C26H43BrO9
CAS Number:
Molecular Weight:
579.52
Beilstein:
3576922
MDL number:
UNSPSC Code:
12352201
PubChem Substance ID:
Assay
≥90% (TLC)
form
powder
optical activity
[α]/D 152.0±3.0°, c = 3 in chloroform
storage temp.
2-8°C
SMILES string
CC(C)(C)C(=O)OC[C@H]1O[C@H](Br)[C@H](OC(=O)C(C)(C)C)[C@@H](OC(=O)C(C)(C)C)[C@@H]1OC(=O)C(C)(C)C
InChI
1S/C26H43BrO9/c1-23(2,3)19(28)32-13-14-15(34-20(29)24(4,5)6)16(35-21(30)25(7,8)9)17(18(27)33-14)36-22(31)26(10,11)12/h14-18H,13H2,1-12H3/t14-,15-,16+,17-,18+/m1/s1
InChI key
BSDBCYHGMPHOAL-SFFUCWETSA-N
Application
Königs-Knorr glycosyl donor with considerably lower tendency to form orthoester side products during glycosylation than the traditional acetobromoglucose
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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A. Presser et al.
Monatshefte fur Chemie / Chemical Monthly, 137, 365-365 (2006)
H. Kunz and A. Harreus
Liebigs Ann. Chem., 717-730 (1986)
H. Kunz and A. Harreus
Liebigs Ann. Chem., 41-48 (1982)
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