790850
(S)-3,3′-Bis(4-trifluoromethylphenyl)-1,1′-binaphthyl-2,2′-disulfonimide
Synonym(s):
(11bS)-2,6-Bis[4-(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide
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About This Item
InChI
1S/C34H19F6NO4S2/c35-33(36,37)23-13-9-19(10-14-23)27-17-21-5-1-3-7-25(21)29-30-26-8-4-2-6-22(26)18-28(20-11-15-24(16-12-20)34(38,39)40)32(30)47(44,45)41-46(42,43)31(27)29/h1-18,41H
SMILES string
O=S(C1=C(C2=C(C=CC=C3)C3=CC(C4=CC=C(C(F)(F)F)C=C4)=C2S5(=O)=O)C6=C(C=CC=C6)C=C1C7=CC=C(C(F)(F)F)C=C7)(N5)=O
InChI key
FQLCMGCITBTGMR-UHFFFAOYSA-N
form
solid
reaction suitability
reaction type: Aldol Reaction, reaction type: Allylation, reaction type: Carbonyl/Imine Addition, reaction type: Friedel-Crafts Alkylation
mp
340-360 °C
Application
A Powerful Chiral Counteranion Motif for Asymmetric Catalysis
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
Asymmetric counteranion-directed catalysis (ACDC) has a number of valuable applications in enantioselective synthesis.
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