794449
6-O-Acryloyl-1,2:3,4-bis-O-(1-methylethylidene)-α-D-galactopyranose
contains MEHQ as inhibitor
Synonym(s):
1,2:3,4-Di-O-isopropylidene-6-O-acryloyl-α-D-galactopyranose, AGP, protected pyranose acrylate
InChI
1S/C15H22O7/c1-6-9(16)17-7-8-10-11(20-14(2,3)19-10)12-13(18-8)22-15(4,5)21-12/h6,8,10-13H,1,7H2,2-5H3/t8-,10+,11+,12-,13-/m1/s1
InChI key
PVHFRWORCBIGDM-UUWLPUTASA-N
SMILES string
CC1(O[C@@H]([C@H]([C@@H](COC(C=C)=O)O2)O1)[C@@H](O3)[C@H]2OC3(C)C)C
form
powder
contains
MEHQ as inhibitor
mp
47-52 °C
storage temp.
2-8°C
Application
This monomer can be used to make macromolecules containing carbohydrate moieties. Controlled Radical Polymerization; such as NMP, RAFT, or ATRP, is commonly employed to synthesize well-defined glycopolymers.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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S R Simon Ting et al.
Biomacromolecules, 10(2), 342-352 (2009-01-23)
Hollow poly(6-O-acryloyl-alpha-D-galactopyranose) (PAGP) nanospheres were prepared in a facile manner using the RAFT (reversible addition fragmentation chain transfer) process. Initially, an amphiphilic block copolymer, poly(lactide)-block-poly(6-O-acryloyl-alpha-D-galactopyranose) (PLA-b-PAGP), was synthesized using a poly(lactide) (PLA) macroRAFT agent. It was attained in high yields
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