795682
(4R,4′R,5S,5′S)-2,2′-(1-Methylethylidene
95%
Synonym(s):
2,2-Bis[2-(4R,5S-diphenyl-1,3-oxazolinyl)]propane
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About This Item
InChI
1S/C33H30N2O2/c1-33(2,31-34-27(23-15-7-3-8-16-23)29(36-31)25-19-11-5-12-20-25)32-35-28(24-17-9-4-10-18-24)30(37-32)26-21-13-6-14-22-26/h3-22,27-30H,1-2H3/t27-,28-,29+,30+/m1/s1
SMILES string
CC(C1=N[C@H](C2=CC=CC=C2)[C@H](C3=CC=CC=C3)O1)(C)C4=N[C@H](C5=CC=CC=C5)[C@H](C6=CC=CC=C6)O4
InChI key
ZWWGNCSTEMMQOQ-XAZDILKDSA-N
assay
95%
form
solid
mp
164-169 °C
functional group
ether, phenyl
Quality Level
Related Categories
Application
- To prepare selective exo-catalysts for enantioselective 1,3-dipolar cycloaddition reactions.
- In the asymmetric aminooxygenation of alkenes in the presence of tetramethylaminopyridyl radical (TEMPO) as an oxidant and copper(II) triflate as a catalyst.
- In asymmetric aminofluorination of olefins using an iron catalyst.
This chiral Box ligand was most recently shown to mediate an asymmetric aminofluorination of olefins utlizing Xtalfuor-E (719439) and TREAT-HF (344648). The resulting cyclic carbamates can be readily converted into their concomitant beta-fluoro amino acids.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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