798975
Trovitch Ni-Precatalyst
Synonym(s):
(Ph2PPrDI)Ni
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About This Item
form
powder
reaction suitability
core: nickel
reagent type: catalyst
storage temp.
2-8°C
SMILES string
CC(/C(C)=N/CCCP(C1=CC=CC=C1)C2=CC=CC=C2)=N\CCCP(C3=CC=CC=C3)C4=CC=CC=C4.[Ni]
InChI
1S/C34H38N2P2.Ni/c1-29(35-25-15-27-37(31-17-7-3-8-18-31)32-19-9-4-10-20-32)30(2)36-26-16-28-38(33-21-11-5-12-22-33)34-23-13-6-14-24-34;/h3-14,17-24H,15-16,25-28H2,1-2H3;/b35-29+,36-30+;
InChI key
ILRLBVPENGSFTO-CAKVIZMISA-N
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
Related Content
The Trovitch laboratory is working to develop first-row transition metal catalysts that can be used to achieve a variety of organic transformations. The first complexes from this group made available through Sigma-Aldrich are the hydrosilylation catalysts, (Ph2PPrPDI)Mn and (Ph2PPrDI)Ni. Although these compounds are formally zerovalent, both feature a reduced chelate that coordinates to the metal center beyond its redox non-innocent core.
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