804010
Co(salen,t-Bu, t-Bu)Cl
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About This Item
form
powder
reaction suitability
reagent type: catalyst
core: cobalt
mp
250 °C
storage temp.
2-8°C
SMILES string
Cl[Co]1OC(C(C(C)(C)C)=CC(C(C)(C)C)=C2)=C2/C=N/[C@](CCCC3)([H])[C@@]3([H])/N=C/C(C=C(C(C)(C)C)C=C4C(C)(C)C)=C4O1
InChI
1S/C36H54N2O2.ClH.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1
InChI key
DIPYCKRNYQWVPM-RUIQGICGSA-K
Application
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Shenvi lab repurposed Jacobsen’s cobalt chloride complex for positional isomerization of terminal alkenes via reversible hydrogen atom transfer.