804444
Potassium 4-bromobenzoyltrifluoroborate
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About This Item
Empirical Formula (Hill Notation):
C7H4BBrF3KO
Molecular Weight:
290.91
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Form:
powder
SMILES string
O=C(B(F)(F)F)C1=CC=C(Br)C=C1.[K]
InChI
1S/C7H4BBrF3O.K.H/c9-6-3-1-5(2-4-6)7(13)8(10,11)12;;/h1-4H;;
InChI key
VDBVNKMIMQHLRF-UHFFFAOYSA-N
form
powder
Application
Potassium acyltrifluroborates (KAT′s) are bench, air and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group.
Other Notes
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Bode Group creates N-mesityl-NHC catalysts for enantioselective annulations and SnAP reagents for one-pot aldehyde conversion into N-heterocycles.
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