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804576

Sigma-Aldrich

(1E)-4-Hydroxy-1-mesityl-4-methylpent-1-en-3-one

Synonym(s):

Bode Hydroxamic Acid

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20 EA
CN¥3,228.10

CN¥3,228.10


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20 EA
CN¥3,228.10

About This Item

Empirical Formula (Hill Notation):
C15H20O2
CAS Number:
Molecular Weight:
232.32
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22

CN¥3,228.10


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form

crystals

mp

75-77 °C

functional group

hydroxyl
ketone

SMILES string

O=C(C(C)(C)O)/C=C/C1=C(C)C=C(C)C=C1C

InChI

1S/C15H20O2/c1-10-8-11(2)13(12(3)9-10)6-7-14(16)15(4,5)17/h6-9,17H,1-5H3/b7-6+

InChI key

MZEPKOZFBZWACD-VOTSOKGWSA-N

Application

The following hydroxamic acid was shown by Bode and coworkers to assist in the kinetic resolution of cyclic amines through acylation of one enantiomer, which can be controlled using either the (R,S)- or (S,R)-Bode Kinetic Resolution Catalyst, both of which are also available through Sigma-Aldrich. 

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Mayenite based supports for atmospheric NOx sampling
Cucciniello, R., et al.
Atmospheric Environment, 79, 666-671 (2013)
Spatial and temporal variability of ammonia and other inorganic aerosol species
Day, D.E., et al.
Atmospheric Environment, 61, 490-498 (2012)
Monitoring of NO2 in the ambient air with passive samplers before and after a road reconstruction event
Stranger, M., et al.
Microchemical Journal, Devoted to the Application of Microtechniques in All Branches of Science, 90 (2), 93-98 (2008)
A Piechocki-Minguy et al.
The Science of the total environment, 366(1), 55-64 (2005-09-13)
Personal NO(2) exposure measurements were achieved during two campaigns in a large northern France city. These campaigns were following an innovating approach based on sequential exposure measurements by diffusive samplers distinguishing four categories of microenvironments ("home", "other indoor places", "transport"
Volatile aldehydes in libraries and archives
Fenech, A., et al.
Atmospheric Environment, 44 (17), 2067-2073 (2010)

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