804576
(1E)-4-Hydroxy-1-mesityl-4-methylpent-1-en-3-one
Synonym(s):
Bode Hydroxamic Acid
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About This Item
Empirical Formula (Hill Notation):
C15H20O2
CAS Number:
Molecular Weight:
232.32
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22
SMILES string
O=C(C(C)(C)O)/C=C/C1=C(C)C=C(C)C=C1C
InChI
1S/C15H20O2/c1-10-8-11(2)13(12(3)9-10)6-7-14(16)15(4,5)17/h6-9,17H,1-5H3/b7-6+
InChI key
MZEPKOZFBZWACD-VOTSOKGWSA-N
form
crystals
mp
75-77 °C
functional group
hydroxyl
ketone
Application
The following hydroxamic acid was shown by Bode and coworkers to assist in the kinetic resolution of cyclic amines through acylation of one enantiomer, which can be controlled using either the (R,S)- or (S,R)-Bode Kinetic Resolution Catalyst, both of which are also available through Sigma-Aldrich.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Related Content
Bode Group creates N-mesityl-NHC catalysts for enantioselective annulations and SnAP reagents for one-pot aldehyde conversion into N-heterocycles.
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