804649
(Ethylthio-trifluoroborate)-methane dimethyliminium
95%
Synonym(s):
Bode KAT Reagent
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About This Item
Empirical Formula (Hill Notation):
C5H11BF3NS
CAS Number:
Molecular Weight:
185.02
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
Assay
95%
form
solid
storage temp.
2-8°C
SMILES string
F[B-](F)(F)C(SCC)=[N+](C)C
InChI
1S/C5H11BF3NS/c1-4-11-5(10(2)3)6(7,8)9/h4H2,1-3H3
InChI key
FOEJEMWJAWZDLW-UHFFFAOYSA-N
Application
Reagent is a benchtop stable solid used in the preparation of potassium acyltrifluoroborates(KAT′s). Reported reaction conditions require 1.0 equiv. of n-BuLi(in hexane) at -78°C from the corresponding aryl/heteroaryl halide. Resulting KAT′s can be isolated without needing column chromatography.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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Bode Group creates N-mesityl-NHC catalysts for enantioselective annulations and SnAP reagents for one-pot aldehyde conversion into N-heterocycles.
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