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Merck
CN

805866

i-Butylammonium iodide

greener alternative

Synonym(s):

2-Methylpropan-1-aminium iodide, i-Butylamine hydriodide, Greatcell Solar®

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About This Item

Empirical Formula (Hill Notation):
C4H12IN
Molecular Weight:
201.05
NACRES:
NA.23
PubChem Substance ID:
329768967
UNSPSC Code:
12352101
MDL number:
MFCD28384147

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InChI

1S/C4H11N.HI/c1-4(2)3-5;/h4H,3,5H2,1-2H3;1H

SMILES string

CC(C)CN.I

InChI key

FCTHQYIDLRRROX-UHFFFAOYSA-N

assay

98%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

168.2 °C

greener alternative category

, Enabling

General description

i-Butlyammonium iodide (iso-BAI) is an ammonium salt that facilitates the formation of highly stable perovskites with good performance. These perovskite materials act as moisture resistant light absorbers. The butylamine is used as a spacing ammonium cation that supports the insulation of 2D perovskites.
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Application

Iso-BAI in combination with formamidinium iodide (FAI) forms a mixture of bulky organic ammonium iodide, which is used in the fabrication of perovskite based solar cells with a power conversion efficiency of > 21%.
The iodide and bromide based alkylated halides find applications as precursors for fabrication of perovskites for photovoltaic applications.

Legal Information

Product of Greatcell Solar®
Greatcell Solar is a registered trademark of Greatcell Solar

pictograms

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GHS07

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Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBW2462

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Mixed 3D-2D Passivation Treatment for Mixed-Cation Lead Mixed-Halide Perovskite Solar Cells for Higher Efficiency and Better Stability
Cho Y, et al.
Advanced Energy Materials, 8(20), 1703392-1703392 (2018)
Attaining High Photovoltaic Efficiency and Stability with Multidimensional Perovskites
Kosasih FU and Ducati C
ChemSusChem, 11(24), 4193-4202 (2018)
Hydrogen bond enables highly efficient and stable two-dimensional perovskite solar cells based on 4-pyridine-ethylamine
Li J, et al.
Organic Electronics, 67(24), 122-127 (2019)
Recent progress in 2D/quasi-2D layered metal halide perovskites for solar cells
Yan J, et al.
Journal of Material Chemistry A, 6(24), 11063-11077 (2018)
Nam Joong Jeon et al.
Nature, 517(7535), 476-480 (2015-01-07)
Of the many materials and methodologies aimed at producing low-cost, efficient photovoltaic cells, inorganic-organic lead halide perovskite materials appear particularly promising for next-generation solar devices owing to their high power conversion efficiency. The highest efficiencies reported for perovskite solar cells
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