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Merck
CN

808016

(R,S,S)-Elenor Amination Reagent

Synonym(s):

3H-3a,6-Methano-2,1-benzisothiazole-1(4H)-carboxamide, tetrahydro-N-hydroxy-8,8-dimethyl-, 2,2-dioxide, (3aR,6S,7aS)-

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About This Item

Empirical Formula (Hill Notation):
C11H18N2O4S
CAS Number:
188845-76-3
Molecular Weight:
274.34
PubChem Substance ID:
329769051
UNSPSC Code:
12352000
Form:
powder

Key Documents

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InChI

1S/C11H18N2O4S/c1-10(2)7-3-4-11(10)6-18(16,17)13(8(11)5-7)9(14)12-15/h7-8,15H,3-6H2,1-2H3,(H,12,14)/t7-,8-,11-/m0/s1

InChI key

FYSORZDAOUCPGD-LAEOZQHASA-N

SMILES string

O=C(N1S(C[C@@]2(C3(C)C)CC[C@@]3([H])C[C@]12[H])(=O)=O)NO

form

powder

functional group

amine, sulfonamide

storage temp.

2-8°C

Application

The following hydroxyamide is a chiral electrophilic nitroso reagent for the transfer of nitrogen to enol ethers. This methology was reported by the Read de Alaniz Group, is a mild approach that can be performed at room temperature and in the presence of air.

Other Notes

Asymmetric Electrophilic α-Amination of Silyl Enol Ether Derivatives via the Nitrosocarbonyl Hetero-ene Reaction

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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