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858919

D-Proline

≥99%, for peptide synthesis, ReagentPlus®

Synonym(s):

(R)-Pyrrolidine-2-carboxylic acid

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About This Item

Empirical Formula (Hill Notation):
C5H9NO2
CAS Number:
344-25-2
Molecular Weight:
115.13
NACRES:
NA.22
PubChem Substance ID:
24888479
UNSPSC Code:
12352209
EC Number:
206-452-7
MDL number:
MFCD00064317
Beilstein/REAXYS Number:
80811
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Product Name

D-Proline, ReagentPlus®, ≥99%

Quality Segment

200

product line

ReagentPlus®

assay

≥99%

form

powder

optical activity

[α]22/D +85.0°, c = 4 in H2O

optical purity

ee: 98% (GLC)

reaction suitability

reaction type: solution phase peptide synthesis

mp

223 °C (dec.) (lit.)

application(s)

peptide synthesis

SMILES string

OC(=O)[C@H]1CCCN1

InChI

1S/C5H9NO2/c7-5(8)4-2-1-3-6-4/h4,6H,1-3H2,(H,7,8)/t4-/m1/s1

InChI key

ONIBWKKTOPOVIA-SCSAIBSYSA-N

Application

D-Proline is a key starting material in the total synthesis of (−)-secu′amamine A and (R)-harmicine.
  • It can be used as a ligand for the synthesis of chiral polyoxometalate (POM) clusters.
  • It can also be used as a catalyst in the enantioselective α-aminoxylation of aldehydes.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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