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Merck
CN

87306

Tetrahexylammonium hydroxide solution

~40% in H2O (T)

Synonym(s):

Tetra(n-hexyl)ammonium hydroxide

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About This Item

Linear Formula:
[CH3(CH2)5]4N(OH)
CAS Number:
17756-56-8
Molecular Weight:
371.68
Beilstein:
6019685
MDL number:
MFCD00059255
UNSPSC Code:
12352106
PubChem Substance ID:
57653238
NACRES:
NA.22

Key Documents

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form

solution

concentration

~40% in H2O (T)

impurities

≤0.1% halides (as bromide)

anion traces

sulfate (SO42-): ≤1000 mg/kg

functional group

amine

SMILES string

[OH-].CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC

InChI

1S/C24H52N.H2O/c1-5-9-13-17-21-25(22-18-14-10-6-2,23-19-15-11-7-3)24-20-16-12-8-4;/h5-24H2,1-4H3;1H2/q+1;/p-1

InChI key

JCJNUSDBRRKQPC-UHFFFAOYSA-M

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Application

Tetrahexylammonium hydroxide is a phase-transfer reagent that can be used:
  • To synthesize β-D-xyloside- and β-D-xylobioside-based ionic liquids containing tetrahexylammonium cation.
  • As an alkali-free gelling agent to prepare amorphous microporous silica-alumina.
  • To synthesize tetrahexylammonium prolinate, a promising candidate to prepare a solid supported ionic liquid phase (SILP) carbon dioxide absorber.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P280 - P305 + P351 + P338 - P310

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK1600
BCCH4446
BCCH8912
BCCH1194
BCCF2981

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Detection of diuretic agents in doping control.
Ventura R and Segura J
Journal of Chromatography. B, Biomedical Sciences and Applications, 687(1), 127-144 (1996)
Mesoporous silica-aluminas as catalysts for the alkylation of aromatic hydrocarbons with olefins.
Perego C, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 27(2-3), 345-354 (1999)
CO 2 Capture technologies: Current status and new directions using supported ionic liquid phase (SILP) absorbers.
Kolding H, et al.
Science China: Chemistry, 55(8), 1648-1656 (2012)
Preparation of new ?-D-xyloside-and ?-D-xylobioside-based ionic liquids through chemical and/or enzymatic reactions.
Gatard S, et al.
Carbohydrate Research, 451, 72-80 (2017)
A M Lisi et al.
Journal of chromatography, 581(1), 57-63 (1992-10-02)
A simple and efficient procedure has been developed for the derivatization of diuretic agents in human urine by direct extractive alkylation and their detection by gas chromatography-mass spectrometry. The procedure is an improvement over previous extractive alkylation methods because of
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