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Merck
CN

88125

Tetrapropylammonium (meta)periodate

moistened with water, ≥98.0% (calc. based on dry substance, RT)

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About This Item

Linear Formula:
(CH3CH2CH2)4N(IO4)
CAS Number:
Molecular Weight:
377.26
UNSPSC Code:
12352000
PubChem Substance ID:
EC Number:
285-973-1
MDL number:
Assay:
≥98.0% (calc. based on dry substance, RT)
Form:
crystals
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InChI key

HDTMHCZUXQKRAJ-UHFFFAOYSA-M

InChI

1S/C12H28N.HIO4/c1-5-9-13(10-6-2,11-7-3)12-8-4;2-1(3,4)5/h5-12H2,1-4H3;(H,2,3,4,5)/q+1;/p-1

SMILES string

[O-]I(=O)(=O)=O.CCC[N+](CCC)(CCC)CCC

assay

≥98.0% (calc. based on dry substance, RT)

form

crystals

quality

moistened with water

contains

~10% water as stabilizer

reaction suitability

reagent type: oxidant

mp

181-183 °C (dec.) (lit.)

Application

Reagent for:
  • Preparation of acylnitroso compoubnds used in Diels-Alder reactions

Other Notes

Oxidation reagent, soluble in organic solvents

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 1 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

supp_hazards

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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G.E. Keck
Tetrahedron Letters, 4767-4767 (1978)
G.E. Keck et al.
Tetrahedron, 37, 4007-4007 (1981)
K. Inomata et al.
Bulletin of the Chemical Society of Japan, 53, 565-565 (1980)

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