900416
Nitrogen-doped graphene
Synonym(s):
N-Doped graphene, NDG, NG
form
powder
composition
Carbon, >80 wt. % , Nitrogen, >4 wt. %
color
black
General description
Electrocatalytic oxygen reduction reaction (ORR) onset potential: >-0.1 V (0.1 M KOH vs Ag/AgCl).
This highly exfoliated nitrogen-doped graphene exhibits high electrochemical activity towards oxygen reduction in alkali medium providing an affordable industrial alternative to currently used noble metal-based catalysts (i.e. Pt, Pd). This nitrogen-doped graphene shows high onset potential (ca. 940 mV vs. RHE) carrying out the electrochemical oxygen reduction reaction (ORR) towards a 4 electron pathway avoiding the production of H2O2. Furthermore, this material is reported to be more stable (to MeOH) and durable (CO tolerance) than Pt-based catalysts.This highly exfoliated nitrogen-doped graphene exhibits high electrochemical activity towards oxygen reduction in alkali medium providing an affordable industrial alternative to currently used noble metal-based catalysts (i.e. Pt, Pd). This nitrogen-doped graphene shows high onset potential (ca. 940 mV vs. RHE) carrying out the electrochemical oxygen reduction reaction (ORR) towards a 4 electron pathway avoiding the production of H2O2. Furthermore, this material is reported to be more stable (to MeOH) and durable (CO tolerance) than Pt-based catalysts.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Facile synthesis of mesoporous nitrogen-dopedgraphene: An efficient methanol?tolerantcathodiccatalystfor oxygen reductionreaction.
Conga H, et al.
Nano Energy, 3, 55-63 (2014)
Frédéric Joucken et al.
Scientific reports, 5, 14564-14564 (2015-09-29)
Understanding the modification of the graphene's electronic structure upon doping is crucial for enlarging its potential applications. We present a study of nitrogen-doped graphene samples on SiC(000) combining angle-resolved photoelectron spectroscopy, scanning tunneling microscopy and spectroscopy and X-ray photoelectron spectroscopy
Tao Hu et al.
Physical chemistry chemical physics : PCCP, 16(3), 1060-1066 (2013-11-30)
Chemical doping of nitrogen into graphene can significantly enhance the reversible capacity and cyclic stability of the graphene-based lithium ion battery (LIB) anodes, and first principles calculations based on density functional theory suggested that pyridinic-N shows stronger binding with Li
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