900635
Sodium 2-methylcyclopropylsulfinate
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About This Item
Empirical Formula (Hill Notation):
C4H7NaO2S
Molecular Weight:
142.15
UNSPSC Code:
12352200
Form:
powder or crystals
form
powder or crystals
reaction suitability
reaction type: C-C Bond Formation, reaction type: C-H Activation, reagent type: catalyst
Application
The following Baran sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Pd (II)-Catalyzed Direct Sulfonylation of Unactivated C (sp3)?H Bonds with Sodium Sulfinates.
Rao W H, et al.
Organic Letters, 17(14), 3552-3555 (2015)
Palladium-catalyzed coupling of vinyl tosylates with arylsulfinate salts.
Reeves D C, et al.
Tetrahedron Letters, 50(24), 2870-2873 (2009)
Copper-Catalyzed Aerobic Decarboxylative Sulfonylation of Cinnamic Acids with Sodium Sulfinates: Stereospecific Synthesis of (E)-Alkenyl Sulfones.
Jiang Q, et al.
The Journal of Organic Chemistry, 79(16), 7372-7379 (2014)
Cu-Catalyzed Deoxygenative C2-Sulfonylation Reaction of Quinoline N-Oxides with Sodium Sulfinate.
Du B, et al.
Organic Letters, 18(16), 4144-4147 (2016)
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