900989
1,3,5-Phenyltriboronic acid, tris(pinacol) ester
≥97%
Synonym(s):
1,3,5-Tris(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene
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About This Item
Empirical Formula (Hill Notation):
C24H39B3O6
CAS Number:
Molecular Weight:
456.00
UNSPSC Code:
12352106
NACRES:
NA.06
MDL number:
Assay:
≥97%
Form:
powder or crystals
Quality Level
assay
≥97%
form
powder or crystals
mp
286-287 °C
SMILES string
CC1(C)OB(OC1(C)C)C2=CC(B3OC(C)(C)C(C)(C)O3)=CC(B4OC(C)(C)C(C)(C)O4)=C2
InChI
1S/C24H39B3O6/c1-19(2)20(3,4)29-25(28-19)16-13-17(26-30-21(5,6)22(7,8)31-26)15-18(14-16)27-32-23(9,10)24(11,12)33-27/h13-15H,1-12H3
InChI key
VKOLBYNBPONPAE-UHFFFAOYSA-N
Application
1,3,5-Phenyltriboronic acid, tris(pinacol) ester can undergo Suzuki–Miyaura cross-coupling polycondensation reaction with 4,7-dibromobenzo[c][1,2,5]thiadiazole to afford conjugated polybenzothiadiazoles. It may also be used as a crosslinker for synthesizing conjugated microporous polymer (CMP) nanoparticles. This product was previously listed as BML00299.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Conjugated microporous polymer nanoparticles with enhanced dispersibility and water compatibility for photocatalytic applications.
Ma BC, et al.
Journal of Material Chemistry A, 3, 16064-16071 (2015)
Can Yang et al.
Angewandte Chemie (International ed. in English), 55(32), 9202-9206 (2016-06-16)
The search for metal-free organic photocatalysts for H2 production from water using visible light remains a key challenge. Reported herein is a molecular structural design of pure organic photocatalysts, derived from conjugated polybenzothiadiazoles, for photocatalytic H2 evolution using visible light.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 900989-1G | 04061826068977 |