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Merck
CN

901138

14-Azido-3,6,9,12-tetraoxatetradecan-1-amine

Synonym(s):

2-[2-[2-[2-(2-Azidoethoxy)ethoxy]ethoxy]ethoxy]ethanamine

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About This Item

Empirical Formula (Hill Notation):
C10H22N4O4
CAS Number:
951671-92-4
Molecular Weight:
262.31
UNSPSC Code:
12352125
NACRES:
NA.22
MDL number:
MFCD20134134

Key Documents

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InChI

1S/C10H22N4O4/c11-1-3-15-5-7-17-9-10-18-8-6-16-4-2-13-14-12/h1-11H2

SMILES string

NCCOCCOCCOCCOCCN=[N+]=[N-]

InChI key

ZMBGKXBIVYXREN-UHFFFAOYSA-N

form

liquid

reaction suitability

reagent type: linker

refractive index

n/D 1.45

density

1.10 g/mL

functional group

amine
azide

storage temp.

2-8°C

Quality Level

100

Related Categories

Application

14-Azido-3,6,9,12-tetraoxatetradecan-1-amine is an azide with polyethylene glycol-like characteristics that can be used to prepare fluorescent polymer particles via enzymatic miniemulsion polymerization and copper (I) catalyzed click reaction approach. It is also used as a reactant to synthesize α-aryl-α-diazoamides by aminolysis of N-succinimidyl α-aryl-α-diazoacetates.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F

flash_point_c

110 °C

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV6461
MKCT4219
MKCS2012
MKCP2076
MKCK8433

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A green approach for the synthesis of fluorescent polymer particles by combined use of enzymatic miniemulsion polymerization with clickable surfmer and click reaction
Kohri Michinari, et al.
Transactions of the Materials Research Society of Japan, 39(1), 57-60 (2014)
Joomyung V Jun et al.
Organic letters, 23(8), 3110-3114 (2021-04-06)
α-Aryl-α-diazoamides were synthesized in two steps under mild conditions. This expeditious route employs Pd-catalyzed C-H arylation of N-succinimidyl 2-diazoacetate to obtain N-succinimidyl 2-aryl-2-diazoacetates, followed by aminolysis. The ensuing diazo compounds can esterify carboxyl groups in aqueous solution, and the ester

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