901216
(S)-Ph-quinox
≥95%
Synonym(s):
(S)-4-Phenyl-2-(quinolin-2-yl)-4,5-dihydrooxazole
Sign Into View Organizational & Contract Pricing
Select a Size
About This Item
Empirical Formula (Hill Notation):
C18H14N2O
CAS Number:
Molecular Weight:
274.32
UNSPSC Code:
12352200
Assay
≥95%
form
powder or crystals
reaction suitability
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation
mp
142 °C
Application
(S)-Ph-quinox is a chiral dinitrogen ligand which is used in the iridium-catalyzed enantioselective borylation and silylation of aromatic C-H bonds, in addition to the enantioselective palladium-catalyzed diamination of alkenes. It can also be used in the aza-Wacker-type cyclization reaction of the olefinic tosylamides with molecular oxygen.
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Pd-catalyzed asymmetric aza-Wacker-type cyclization reaction of olefinic tosylamides.
Jiang F, et al.
Tetrahedron Letters, 51(39), 5124-5126 (2010)
Enantioselective Borylation of Aromatic C? H Bonds with Chiral Dinitrogen Ligands.
Su B, et al.
Angewandte Chemie (International Edition in English), 56(25), 7205-7208 (2017)
A Chiral Nitrogen Ligand for Enantioselective, Iridium?Catalyzed Silylation of Aromatic C? H Bonds.
Su B, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 129(4), 1112-1116 (2017)
Erica L Ingalls et al.
Journal of the American Chemical Society, 135(24), 8854-8856 (2013-06-06)
An enantioselective Pd-catalyzed vicinal diamination of unactivated alkenes using N-fluorobenzenesulfonimide as both an oxidant and a source of nitrogen is reported. The use of Ph-pybox and Ph-quinox ligands afforded differentially protected vicinal diamines in good yields with high enantioselectivities. Mechanistic
Articles
QuinoxP*: Air-Stable and Highly Efficient and Productive Chiral Ligands
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service