901272
Dodeca(2,3,4,5,6-pentafluorobenzyloxy)-hypercloso-dodecaborane
Synonym(s):
Dodecaborate clusters, Metal-free photooxidant
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Empirical Formula (Hill Notation):
C84H24B12F60O12
Molecular Weight:
2494.72
UNSPSC Code:
12352101
NACRES:
NA.23
SMILES string
FC1=C(F)C(F)=C(F)C(F)=C1COB2B(OCC3=C(F)C(F)=C(F)C(F)=C3F)B(OCC4=C(F)C(F)=C(F)C(F)=C4F)B5(OCC6=C(F)C(F)=C(F)C(F)=C6F)B(OCC7=C(F)C(F)=C(F)C(F)=C7F)[B@](B(OCC8=C(F)C(F)=C(F)C(F)=C8F)B(OCC9=C(F)C(F)=C(F)C(F)=C9F)B(OCC%10=C(F)C(F)=C(F)C(F)=C%10F)B5OCC%11=C(F)C
form
powder
Application
Icosahedral dodecaborate clusters of the type B12(OCH2C6F5)12 are new class of metal-free photooxidants able to undergo photoexcitation with visible light. These clusters have been utilized for the oxidation of both activated and unactivated olefins in the presence of blue light, leading to their polymerization.
Legal Information
Sold under Material Transfer Agreement with Prof. Alexander Spokoyny from Department of Chemistry and Biochemistry, UCLA.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Alex I Wixtrom et al.
Inorganic chemistry frontiers, 3(5), 711-717 (2016-11-26)
We have developed a fast and efficient route to obtain perfunctionalized ether-linked alkyl and benzyl derivatives of the
Marco S Messina et al.
Journal of the American Chemical Society, 138(22), 6952-6955 (2016-05-18)
We report a discovery that perfunctionalized icosahedral dodecaborate clusters of the type B12(OCH2Ar)12 (Ar = Ph or C6F5) can undergo photo-excitation with visible light, leading to a new class of metal-free photooxidants. Excitation in these species occurs as a result
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service