901417
N-((1S,2S)-1-((R)-4-Isobutyl-4,5-dihydrooxazol-2-yl)-2-methylbutyl)acetamide
Synonym(s):
Chiral APAO ligand
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About This Item
Empirical Formula (Hill Notation):
C14H26N2O2
CAS Number:
Molecular Weight:
254.37
UNSPSC Code:
12352202
Form:
powder or crystals
form
powder or crystals
reaction suitability
reagent type: catalyst, reagent type: ligand
reaction type: C-H Activation
storage temp.
−20°C
Application
Chiral bidentate ligand developed by Jin-Quan Yu.′s lab for enantioselective borylation of C(sp3)–H bonds. This acetyl-protected aminomethyl oxazoline (APAO) ligand was demonstrated to be compatible with carbocyclic substrates with both α-tertiary and α-quaternary carbon centres.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Jian He et al.
Journal of the American Chemical Society, 139(9), 3344-3347 (2017-02-18)
Pd(II)-catalyzed enantioselective borylation of C(sp
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