901591
18-Crown-6 solution
1.0 M in THF, liquid
Sustainability features
Synonym(s):
1,4,7,10,13,16-Hexaoxacyclooctadecane
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About This Item
Linear Formula:
C12H24O6
CAS Number:
UNSPSC Code:
12352005
NACRES:
NA.22
MDL number:
eCl@ss:
32039090
Form:
liquid
Product Name
18-Crown-6 solution, 1.0 M in THF
form
liquid
reaction suitability
core: crown ether, reaction type: phase-transfer
sustainability
Sustainability features
concentration
1.0 M in THF
density
0.944 g/mL
SMILES string
O1CCOCCOCCOCCOCCOCC1
InChI
1S/C12H24O6/c1-2-14-5-6-16-9-10-18-12-11-17-8-7-15-4-3-13-1/h1-12H2
InChI key
XEZNGIUYQVAUSS-UHFFFAOYSA-N
General description
This product aligns with one or more of the 12 Principles of Green Chemistry Click here for more information.
Application
Phase-transfer catalyst used in a chemoselective reduction of fused tetrazoles with NaBH4 and potassium hydroxide.
18-Crown-6 may be used to catalyze the N-alkylation of heterocyclic compounds and allylation of functionalized aldehydes.
Additive for greener etherification using KF-alumina.
Additive for greener etherification using KF-alumina.
Synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6
Synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6
Signal Word
Danger
supp_hazards
Storage Class
3 - Flammable liquids
Flash Point (°F)
-2.0 °F
Flash Point (°C)
-18.88 °C
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
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