901821
Benzene-1,3,5-triyl triformate
Synonym(s):
TFBen
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About This Item
Empirical Formula (Hill Notation):
C9H6O6
CAS Number:
Molecular Weight:
210.14
UNSPSC Code:
12352200
form
powder or crystals
reaction suitability
reaction type: C-C Bond Formation
mp
53-56
storage temp.
2-8°C
Application
Benzene-1,3,5-triyl triformate (TFBen) has been demonstrated to be an efficient and non-reacting CO source for carbonylation reactions in the lab of Xiao-Feng Wu.
Other Notes
Benzene-1,3,5-triyl triformate (TFBen): a convenient, efficient, and non-reacting CO source in carbonylation reactions
A general and practical Lewis acids-catalyzed aryl formates synthesis
DBU-promoted carbonylative synthesis of 1,3-oxathiolan-2-ones from propargylic alcohols with TFBen as the CO source
Base-Promoted Sulfur-Mediated Carbonylative Cyclization of Propargylic Amines
A general and practical Lewis acids-catalyzed aryl formates synthesis
DBU-promoted carbonylative synthesis of 1,3-oxathiolan-2-ones from propargylic alcohols with TFBen as the CO source
Base-Promoted Sulfur-Mediated Carbonylative Cyclization of Propargylic Amines
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Benzene-1,3,5-triyl triformate (TFBen): a convenient, efficient, and non-reacting CO source in carbonylation reactions.
Jiang LB, et al.
Tetrahedron Letters, 57, 3368-3370 (2016)
Base-Promoted Sulfur-Mediated Carbonylative Cyclization of Propargylic Amines.
Ying J, et al.
European Journal of Organic Chemistry, 2018(5), 688-692 (2018)
A general and practical Lewis acids-catalyzed aryl formates synthesis.
Jiang LB , et al.
Molecular Catalysis, 433, 8-11 (2017)
Jun Ying et al.
Organic & biomolecular chemistry, 16(7), 1065-1067 (2018-01-25)
A DBU-promoted carbonylative cyclization of propargylic alcohols with sulfur was developed. Various 1,3-oxathiolan-2-ones were produced in 61-98% yields under mild conditions in the absence of metal catalysts. TFBen (benzene-1,3,5-triyl triformate) as an efficient and solid CO surrogate and S
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