902144
[(Cp)Ru(η6-naphthalene)]OTf
≥95%
Synonym(s):
(η5-Cyclopentadienyl)(η6-naphthalene)ruthenium(1+) trifluoromethanesulfonate
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About This Item
Empirical Formula (Hill Notation):
C16H13F3O3RuS
CAS Number:
Molecular Weight:
443.40
MDL number:
UNSPSC Code:
12352101
Assay
≥95%
form
powder
reaction suitability
reagent type: catalyst
reaction type: C-C Bond Formation
mp
112-116 °C
storage temp.
2-8°C
Application
Stable precursor for synthesis and ruthenium catalysis. It was also used by the Ritter lab to synthesize an Fmoc-protected ruthenium tyrosine for subsequent incorporation of the [18F]fluoride radiolabel into polypeptides.
Other Notes
Site-Specific Deoxyfluorination of Small Peptides with [18F]Fluoride
Comparison of the Catalytic Activity of [(5-C5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(5-C5H5)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions
Arene Exchange in the Ruthenium-Naphthalene Complex [CpRu(C10H8)]+
Comparison of the Catalytic Activity of [(5-C5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(5-C5H5)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions
Arene Exchange in the Ruthenium-Naphthalene Complex [CpRu(C10H8)]+
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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Jens Rickmeier et al.
Angewandte Chemie (International ed. in English), 57(43), 14207-14211 (2018-09-07)
Radiolabeled receptor-binding peptides are an important class of positron emission tomography tracers owing to achievable high binding affinities and their rapid blood clearance. Herein, a method to introduce a 4-[18 F]fluoro-phenylalanine residue into peptide sequences is reported, by chemoselective radio-deoxyfluorination
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