Skip to Content
Merck
CN

Key Documents

View All Documentation

904104

CoCl2(PCy3)2

powder or crystals

Synonym(s):

Dichlorobis(tricyclohexylphosphine)cobalt(II)

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):
C36H66Cl2CoP2
CAS Number:
14726-62-6
Molecular Weight:
690.70
MDL number:
MFCD31807340
UNSPSC Code:
12352101
NACRES:
NA.22
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

CoCl2(PCy3)2,

form

powder or crystals

reaction suitability

core: cobalt, reagent type: catalyst

mp

>300 °C

SMILES string

[Co](Cl)Cl.P(C6CCCCC6)(C5CCCCC5)C4CCCCC4.P(C3CCCCC3)(C2CCCCC2)C1CCCCC1

InChI

1S/2C18H33P.2ClH.Co/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*16-18H,1-15H2;2*1H;/q;;;;+2/p-2

InChI key

XTBDMUPZCVAWRK-UHFFFAOYSA-L

Application

This cobalt catalyst can be used in conjunction with the photocatalyst (Ir[dF(CF3)ppy]2(dtbpy))PF6(747793) for the [2+2+2] alkyne cycloaddition.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Visible light-gated cobalt catalysis for a spatially and temporally resolved [2+2+2] cycloaddition

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
SHBS7600

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Kyle E Ruhl et al.
Journal of the American Chemical Society, 138(48), 15527-15530 (2016-12-10)
The ability to exert spatial and temporal control over a transition-metal catalyst offers diverse opportunities for the fabrication of functional materials. Using an external stimulus such as visible light to toggle a catalyst between an active and dormant state has