904104
CoCl2(PCy3)2
powder or crystals
Synonym(s):
Dichlorobis(tricyclohexylphosphine)cobalt(II)
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About This Item
Empirical Formula (Hill Notation):
C36H66Cl2CoP2
CAS Number:
Molecular Weight:
690.70
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
Product Name
CoCl2(PCy3)2,
SMILES string
[Co](Cl)Cl.P(C6CCCCC6)(C5CCCCC5)C4CCCCC4.P(C3CCCCC3)(C2CCCCC2)C1CCCCC1
InChI
1S/2C18H33P.2ClH.Co/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*16-18H,1-15H2;2*1H;/q;;;;+2/p-2
InChI key
XTBDMUPZCVAWRK-UHFFFAOYSA-L
form
powder or crystals
reaction suitability
core: cobalt
reagent type: catalyst
mp
>300 °C
Related Categories
Application
This cobalt catalyst can be used in conjunction with the photocatalyst (Ir[dF(CF3)ppy]2(dtbpy))PF6(747793) for the [2+2+2] alkyne cycloaddition.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Kyle E Ruhl et al.
Journal of the American Chemical Society, 138(48), 15527-15530 (2016-12-10)
The ability to exert spatial and temporal control over a transition-metal catalyst offers diverse opportunities for the fabrication of functional materials. Using an external stimulus such as visible light to toggle a catalyst between an active and dormant state has
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