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Merck
CN

905879

[Pd(terpy)(MeCN)][BF4]2

≥95%, powder or crystals

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About This Item

Empirical Formula (Hill Notation):
C17H14B2F8N4Pd
CAS Number:
152101-13-8
Molecular Weight:
554.35
MDL number:
MFCD31807348
UNSPSC Code:
12161600
NACRES:
NA.22

Key Documents

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Product Name

[Pd(terpy)(MeCN)][BF4]2, ≥95%

InChI

1S/C15H11N3.C2H3N.Pd/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13;1-2-3;/h1-11H;1H3;

InChI key

UESWWXSSNHGEKT-UHFFFAOYSA-N

SMILES string

N#CC.C1(C2=CC=CC=N2)=CC=CC(C3=NC=CC=C3)=N1.[Pd]

assay

≥95%

form

powder or crystals

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

>300 °C

storage temp.

2-8°C

Related Categories

Application

[Pd(terpy)(MeCN)][BF4]2 is a versatile palladium precatalyst.
Automate your fluorination reactions with Synple Automated Synthesis Platform (SYNPLE-SC002)

Other Notes

Palladium(III)-Catalyzed Fluorination of Arylboronic Acid Derivatives

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP1997

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Anthony R Mazzotti et al.
Journal of the American Chemical Society, 135(38), 14012-14015 (2013-09-18)
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated
Kumiko Yamamoto et al.
Nature, 554(7693), 511-514 (2018-02-23)
Aryl fluorides are widely used in the pharmaceutical and agrochemical industries, and recent advances have enabled their synthesis through the conversion of various functional groups. However, there is a lack of general methods for direct aromatic carbon-hydrogen (C-H) fluorination. Conventional

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