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Merck
CN

911941

Sigma-Aldrich

2-((Perfluorooctyl)sulfonyl)-1-phenylpropan-1-one

≥95%

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About This Item

Empirical Formula (Hill Notation):
C17H9F17O3S
Molecular Weight:
616.29
UNSPSC Code:
12352101
NACRES:
NA.22

Key Documents

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Assay

≥95%

form

powder

reaction suitability

reaction type: C-C Bond Formation

mp

99-101 °C

Related Categories

Application

2-((Perfluorooctyl)sulfonyl)-1-phenylpropan-1-one is part of a suite of reagents developed by the Li group for late-stage functionalization of pharmaceutically relevant compounds. The reagents serve as precursors to alkyl radicals generated under light mediated, redox-neutral and catalyst free conditions for use in the Minisci alkylation of aromatics.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Catalyst-Free and Redox-Neutral Innate Trifluoromethylation and Alkylation of Aromatics Enabled by Light

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Lact. - Repr. 1B - STOT RE 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Peng Liu et al.
Journal of the American Chemical Society, 139(40), 14315-14321 (2017-10-03)
The Minisci alkylation is useful to functionalize aromatics via alkyl radical addition. Current approaches to prepare alkyl radicals follow either oxidative or reductive pathways from various functional groups. Developing new strategy beyond these traditional methods remains elusive yet highly significant.

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