912522
Adamantanyl 2,2-diiodoacetate
≥95%
Synonym(s):
Suero cyclopropanation reagent
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About This Item
Empirical Formula (Hill Notation):
C12H16I2O2
CAS Number:
Molecular Weight:
446.06
UNSPSC Code:
12352200
Assay:
≥95%
Form:
powder or crystals
assay
≥95%
form
powder or crystals
reaction suitability
reaction type: C-C Bond Formation
mp
94-95 °C
storage temp.
2-8°C
Application
Adamantanyl 2,2-diiodoacetate is a photocyclopropanation reagent capable of late-stage functionalization. The cyclopropanation of styrenes proceeds in the presence of visible light, without the need of a photocatalyst.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Legal Information
This product is not available in Europe.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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A transition-metal-free & diazo-free styrene cyclopropanation
Herraiz A G and Suero M G
Chemical Science, 10, 9374-9379 (2019)
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The Suero research group has developed new catalytic methods involving conceptually-novel radical carbenoids, carbyne equivalents, and metal-carbynoids and studied their behavior towards fine & feedstock chemicals as well as medically relevant agents.
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