919365
(MeBPI)Ni-OAc
powder
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About This Item
Empirical Formula (Hill Notation):
C22H19N5NiO2
Molecular Weight:
444.11
UNSPSC Code:
12352200
NACRES:
NA.22
Product Name
(MeBPI)Ni-OAc,
form
powder
Quality Level
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Related Categories
Application
(MeBPI)Ni-OAc is a Ni catalyst developed in the Sevov lab for electrocatalytic cross-electrophile coupling reactions. When combined with a redox-active shuttle (918105), (MeBPI)Ni-OAc enables the reductive coupling of a wide range of aryl, heteroaryl, or vinyl bromides with primary or secondary alkyl bromides.
Product can be used with our Synlectro electrochemistry platform (ESYNTH001)
Product can be used with our Synlectro electrochemistry platform (ESYNTH001)
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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Blaise L Truesdell et al.
Journal of the American Chemical Society, 142(12), 5884-5893 (2020-03-03)
Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction can readily exceed the reducing potentials of chemical reductants to activate catalysts
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