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Merck
CN

921025

Palladium(II) acetylacetonate

≥99.9% trace metals basis

Synonym(s):

Palladium(II) 2,4-pentanedionate, Pd(acac)2

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About This Item

Linear Formula:
Pd(C5H7O2)2
CAS Number:
14024-61-4
Molecular Weight:
304.64
NACRES:
NA.23
UNSPSC Code:
12161600
Beilstein/REAXYS Number:
4136188
MDL number:
MFCD00000025
Assay:
≥99.9% trace metals basis

Key Documents

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Product Name

Palladium(II) acetylacetonate, ≥99.9% trace metals basis

SMILES string

CC(=O)\C=C(\C)O[Pd]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChI key

JKDRQYIYVJVOPF-FDGPNNRMSA-L

assay

≥99.9% trace metals basis

reaction suitability

core: palladium

mp

200-251 °C (dec.)

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

Quality Level

200

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Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Palladium(II) 2,4-pentanedionate can be used to synthesize palladium(II) complexes applicable in common cross-coupling reactions like Suzuki, Heck and Buchwald-Hartwig coupling. As a palladium precursor, it can be used to synthesize hollow Pd/Pt single-crystalline nanocubes with enhanced electrocatalytic activity due to increased surface area. The surface modification of TiO2 using Pd(acac)2 as a metal-organic precursor has enhanced its photocatalytic activity under UV irradiation. Pd(acac)2 can also be used to develop bimetallic alloy NP catalysts applicable in formic acid dehydrogenation.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ3026
MKCX0288
MKCV9411
MKCV6991
MKCT8254

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Deposition of Pd nanoparticles on TiO2 using a Pd (acac)2 precursor for photocatalytic oxidation of CO under UV-LED irradiation.
Selishchev D S, et al.
Applied Catalysis. B, Environmental, 235, 214-224 (2018)
Önder Metin et al.
Nanoscale, 5(3), 910-912 (2012-12-21)
Monodisperse 4 nm AuPd alloy nanoparticles with controlled composition were synthesized by co-reduction of hydrogen tetrachloroaurate(III) hydrate and palladium(II) acetylacetonate with a borane-morpholine complex in oleylamine. These NPs showed high activity (TOF = 230 h(-1)) and stability in catalyzing formic
Madhu Bala et al.
Turkish journal of biology = Turk biyoloji dergisi, 43, 154-154 (2019-08-15)
[This corrects the article DOI: 10.3906/biy-1412-46.].
New insights into catalysis for Heck reactions with fine supported Pd particles.
Huang L, et al.
Reaction Chemistry & Engineering, 5(5), 921-934 (2020)
Xiaoqing Huang et al.
Angewandte Chemie (International ed. in English), 48(26), 4808-4812 (2009-05-16)
Efficiency simplified: A synthetic strategy has been developed to prepare single-crystalline hollow Pd/Pt nanocubes (right, see picture; left: nanocubes). Compared to the solid Pd/Pt nanocubes of similar sizes, the hollow Pd/Pt nanocubes increase accessible surface area and therefore improve electrocatalytic
View All Related Papers

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