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Merck
CN

922722

O-Pivaloylhydroxyamine triflic acid

别名:

2,2-dimethyl-, azanyl ester, 1,1,1-trifluoromethanesulfonate, PivONH3OTF, Propanoic acid

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关于此项目

经验公式(希尔记法):
C5H11NO2 · CHF3O3S
化学文摘社编号:
分子量:
267.22
MDL number:
UNSPSC Code:
12352106
NACRES:
NA.22
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form

solid

Quality Segment

functional group

fluoro, triflate

SMILES string

FC(F)(F)[S](=O)(=O)[O-].[N+H3]OC(=O)C(C)(C)C

InChI key

AJUKGKFBUGZGSW-UHFFFAOYSA-M

Application

This hydroxylamine-based reagent enables the iron-catalyzed selective transformation of thiols to sulfinamides under mild conditions without the use of precious metal catalysts or additional oxidants. This reagent is shelf stable and facilitates the reaction in a single step and under mild conditions.


pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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