922889
DMPDAB-Pd-MAH
≥95%, powder
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About This Item
Empirical Formula (Hill Notation):
C22H22N2O3Pd
CAS Number:
Molecular Weight:
468.84
UNSPSC Code:
12161600
NACRES:
NA.22
Product Name
DMPDAB-Pd-MAH, ≥95%
Quality Level
assay
≥95%
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
SMILES string
O=C1OC(=O)[CH]2=[CH]1[Pd]32[N](=CC=[N]3C=4C(=CC=CC4C)C)C=5C(=CC=CC5C)C
InChI
InChI=1S/C18H20N2.C4H2O3.Pd/c1-13-7-5-8-14(2)17(13)19-11-12-20-18-15(3)9-6-10-16(18)4;5-3-1-2-4(6)7-3;/h5-12H,1-4H3;1-2H;
InChI key
WHOQNDZHEHSRKP-UHFFFAOYSA-N
Application
DMPDAB-Pd-MAH is a Pd(0) source developed by the Leitch group. Ligands of all types, including bidentate phosphines, rapidly displace the diazabutadiene ligand at room temperature to give air-stable Pd(0) complexes.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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DMPDAB?Pd?MAH: A Versatile Pd(0) Source for Precatalyst Formation, Reaction Screening, and Preparative-Scale Synthesis.
Huang J, et al.
ACS Catalysis, 11(9), 5636-5646 (2021)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 922889-1G | 04065266894820 |
| 922889-250MG | 04065266894837 |