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922897

[Ir(ppy)₂(5,5′-Me₂bpy)]PF₆

Name: [Ir(ppy)2(5,5&#8242;-Me2bpy)]PF6
Brand: ALDRICH

≥95%, powder

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About This Item

Empirical Formula (Hill Notation):

C₃₄H₂₈F₆IrN₄P

CAS Number:

808142-82-7

Molecular Weight:

829.79

MDL number:

MFCD34602233

UNSPSC Code:

12352101

NACRES:

NA.22

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Properties

Product Name

[Ir(ppy)₂(5,5′-Me₂bpy)]PF₆, ≥95%

Quality Level

100

assay

≥95%

form

powder

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

SMILES string

[Ir+]741([NH]8=C(c9c7cccc9)C=CC=C8)([NH]5=CC=CC=C5c6c4cccc6)[NH]2=CC(=CC=C2C3=CC=C(C=[NH]31)C)C.F[P-](F)(F)(F)(F)F

InChI

1S/C12H12N2.2C11H8N.F6P.Ir/c1-9-3-5-11(13-7-9)12-6-4-10(2)8-14-12;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h3-8H,1-2H3;2*1-6,8-9H;;/q;;;-1;+1

InChI key

JFNHYYZGRBJZIH-UHFFFAOYSA-N

Description

Application

[Ir(ppy)₂(5,5′-Me₂bpy)]PF₆ is a photoredox catalyst used for a variety of transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Mechanistic Analysis of Metallaphotoredox C-N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Mechanistic Analysis of Metallaphotoredox C-N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity.

Nicholas A Till et al.

Journal of the American Chemical Society, 142(37), 15830-15841 (2020-08-14)

The combined use of reaction kinetic analysis, ultrafast spectroscopy, and stoichiometric organometallic studies has enabled the elucidation of the mechanistic underpinnings to a photocatalytic C-N cross-coupling reaction. Steady-state and ultrafast spectroscopic techniques were used to track the excited-state evolution of

Global Trade Item Number

SKU	GTIN
922897-500MG	04065266894882
922897-100MG	04065266894875