923486
(CyMPhos)PdCl2
powder, complex with CH₂Cl₂
Synonym(s):
1-Diadamantylphosphino-1′-dicyclohexylphosphinoferrocene palladium dichloride
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About This Item
Empirical Formula (Hill Notation):
C42H60Cl2FeP2Pd
CAS Number:
Molecular Weight:
860.04
MDL number:
NACRES:
NA.21
UNSPSC Code:
12352101
Product Name
(CyMPhos)PdCl2, complex with CH2Cl2
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
greener alternative product characteristics
Catalysis
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General description
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Application
(CyMPhos)PdCl2 is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (CyMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).
Learn more about MPhos ligands and catalysts
Learn more about MPhos ligands and catalysts
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Warning
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2?Csp3 Couplings
Xu, et al.
ACS Catalysis, 12, 5123?5135-5123?5135 (2022)
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