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Merck
CN

923486

Sigma-Aldrich

(CyMPhos)PdCl2

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powder, complex with CH₂Cl₂

Synonym(s):

1-Diadamantylphosphino-1′-dicyclohexylphosphinoferrocene palladium dichloride

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About This Item

Empirical Formula (Hill Notation):
C42H60Cl2FeP2Pd
CAS Number:
2768152-20-9
Molecular Weight:
860.04
MDL number:
MFCD01673219
UNSPSC Code:
12352101
NACRES:
NA.21

Key Documents

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Product Name

(CyMPhos)PdCl2, complex with CH2Cl2

Quality Level

100

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

greener alternative product characteristics

Catalysis
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General description

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Application

(CyMPhos)PdCl2 is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (CyMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2–Csp3 Couplings

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H351

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS6913

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Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2?Csp3 Couplings
Xu, et al.
ACS Catalysis, 12, 5123?5135-5123?5135 (2022)

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