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Merck
CN

927120

BTMPO

greener alternative

≥95%, powder

Synonym(s):

N1,N2-Bis(2,4,6-trimethoxyphenyl)ethanediamide

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About This Item

Empirical Formula (Hill Notation):
C20H24N2O8
CAS Number:
Molecular Weight:
420.41
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.21
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Product Name

BTMPO, ≥95%

Quality Level

assay

≥95%

form

powder

reaction suitability

reagent type: ligand
reaction type: Ullmann Reaction

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

SMILES string

O=C(C(NC1=C(OC)C=C(OC)C=C1OC)=O)NC2=C(OC)C=C(OC)C=C2OC

InChI

1S/C20H24N2O8/c1-25-11-7-13(27-3)17(14(8-11)28-4)21-19(23)20(24)22-18-15(29-5)9-12(26-2)10-16(18)30-6/h7-10H,1-6H3,(H,21,23)(H,22,24)

InChI key

NGVJMONAWAGMOA-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

BTMPO is a ligand for the copper-catalyzed coupling of aryl bromides and secondary amines.


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Subhajit Bhunia et al.
The Journal of organic chemistry, 82(23), 12603-12612 (2017-11-09)
N,N'-Bis(furan-2-ylmethyl)oxalamide (BFMO), an inexpensive and conveniently available bidentate ligand, is very effective for promoting Cu-catalyzed N-arylation of anilines and cyclic secondary amines. The method enables coupling of a broad range of (hetero)aryl bromides with various (hetero)aryl amines and cyclic secondary



Global Trade Item Number

SKUGTIN
927120-250MG04065267174730
927120-1G04065267174723