92733
Methyl 3-trimethylsiloxy-2-butenoate
technical, ~86% (trans + ~10% cis)
Synonym(s):
3-Trimethylsiloxy-2-butenoic acid methyl ester, Methyl 3-(trimethylsiloxy)crotonate, Methyl acetoacetate enol trimethylsilylether
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Empirical Formula (Hill Notation):
C8H16O3Si
CAS Number:
Molecular Weight:
188.30
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
263-483-9
MDL number:
Beilstein/REAXYS Number:
2356944
grade
technical
assay
~86% (trans + ~10% cis)
refractive index
n20/D 1.447
bp
43-45 °C/0.3 mmHg (lit.)
density
0.966 g/mL at 20 °C (lit.)
storage temp.
2-8°C
SMILES string
COC(=O)\C=C(/C)O[Si](C)(C)C
Other Notes
Mild and efficient silylating agent; Starting material to 1-methoxy-1,3-bis(trimethylsiloxy)butadiene; a diene for Diels-Alder reactions and an equivalent of the dianien of methyl acetoacetate
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
T.H. Chan et al.
Journal of the Chemical Society. Chemical Communications, 578-578 (1979)
K. Yamamoto et al.
Chemistry Letters (Jpn), 649-649 (1978)
P. Brownbridge et al.
Tetrahedron Letters, 4437-4437 (1979)