930857
Ni(bpy)Cl2
powder
Synonym(s):
[Bipyridine]nickel(II) dichloride
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About This Item
Empirical Formula (Hill Notation):
C10H8Cl2N2Ni
CAS Number:
Molecular Weight:
285.78
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.21
Product Name
Ni(bpy)Cl2,
SMILES string
Cl[Ni]1([N]2=CC=CC=C2C3=CC=CC=[N]31)Cl
form
powder
greener alternative product characteristics
Catalysis
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storage temp.
−20°C
Quality Level
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Application
Ni(bpy)Cl2 is a nickel catalyst used for a variety of cross-coupling reactions.
General description
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Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Synthesis of α-Aryl Secondary Amides via Nickel-Catalyzed Reductive Coupling of Redox-Active Esters.
Alexis L Gabbey et al.
Organic letters, 24(17), 3173-3178 (2022-04-27)
The transition-metal-catalyzed α-arylation of secondary amides remains a synthetic challenge due to the presence of a free N-H bond. We report a strategy to synthesize secondary α-aryl amides via a Ni-catalyzed reductive arylation of redox-active N-hydroxyphthalimide (NHP) esters of malonic
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