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93315

Tris(tert-butyldimethylsilyl) phosphite

≥97.0%

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About This Item

Empirical Formula (Hill Notation):
C18H45O3PSi3
CAS Number:
85197-27-9
Molecular Weight:
424.78
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
57653532
MDL number:
MFCD00077891
Beilstein/REAXYS Number:
4437247
Assay:
≥97.0%
Form:
liquid
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Quality Level

100

assay

≥97.0%

form

liquid

refractive index

n20/D 1.445

bp

82-84 °C/0.2 mmHg

mp

4-6 °C

density

0.907 g/mL at 20 °C (lit.)

SMILES string

CC(C)(C)[Si](C)(C)OP(O[Si](C)(C)C(C)(C)C)O[Si](C)(C)C(C)(C)C

InChI

1S/C18H45O3PSi3/c1-16(2,3)23(10,11)19-22(20-24(12,13)17(4,5)6)21-25(14,15)18(7,8)9/h1-15H3

InChI key

PEHSJBUJMHHQDE-UHFFFAOYSA-N

Other Notes

Reagent used for the preparation of phosphonic acid silyl esters from halides; the TBDMS esters are more stable than the corresponding TMS esters; review

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

190.4 °F - closed cup

flash_point_c

88 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
061163/1
1378109
61163/1

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J.-L. Montero et al.
Tetrahedron Letters, 28, 1163-1163 (1987)
L. Wozniak et al.
Tetrahedron, 45, 2465-2465 (1989)