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Merck
CN

935220

Lithium bis(trifluoromethanesulfonyl)imide solution

in ethylene carbonate and ethylmethylcarbonate, 1.0 M LiTFSI in EC/EMC=50/50 (w/w), battery grade

Synonym(s):

1.0 M LiTFSI in EC/EMC, LiTFSI electrolyte

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About This Item

Linear Formula:
CF3SO2NLiSO2CF3
UNSPSC Code:
26111700
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grade

battery grade

form

solution

concentration

1.0 M (LiTFSI in ethylene carbonate and ethylmethylcarbonate)

impurities

≤100.0 ppm H2O

application(s)

battery manufacturing

Quality Level

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General description

Lithium bis(trifluoromethanesulfonyl)imide in ethylene carbonate and dimethylcarbonate, 1.0 M LiTFSI in EC/EMC=50/50 (w/w) is a solution of battery-grade LiTFSI dissolved in binary mixture of EC/EMC (50:50) wt%. The product is a clear solution with strictly minimized impurities including low moisture (≤100 ppm), low trace metals (≤10 ppm Na and K), low chloride (<10 ppm), and low sulfate (<10 ppm).

Application

The main application of 1.0 M LiTFSI in EC/EMC=50/50 (w/w) is as an electrolyte in Li-ion batteries. Lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) salt are potentially a good alternative to LiPF6 since it could both improve the chemical and thermal stability as salt for electrolyte. The high purity battery grade 1.0 M LiTFSI in EC/EMC=50/50 (w/w) is suitable for R&D activities in LIBS such as oxidative studies of different electrodes, studies on thermal stability in LIBs, Solid electrolyte interphase (SEI) formation etc. In a study with lithium/graphite half cells, it has been observed that, EMC exerted no observable adverse effects on the SEIs or on the kinetics; instead, the addition of EMC was found to reduce low-temperature film resistances and to enhance the kinetics and the discharge characteristics. The best low-temperature electrical performance was observed in the case of the electrolyte with the highest EMC content; this is consistent with the lower (relative to the other carbonate solvents) viscosity and freezing temperature of EMC.

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT RE 2 Oral

target_organs

Kidney,Nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

71.6 °F

flash_point_c

22 °C

Regulatory Information

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Ethyl Methyl Carbonate as a Cosolvent for Lithium-Ion Cells
Smart, Marshall
MATERIALS (2001)
Non-flammable polyphosphonate electrolytes
Dixon Brian G., et al
Journal of Power Sources, 138, 274-276 (2004)
Comparative study on the ionic conductivities and redox properties of LiPF6 and LiTFSI electrolytes and the characteristics of their rechargeable lithium ion batteries
Septiana A R, et al
IOP Conference Series: Materials Science and Engineering, 432 (2017)

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