936111
SerrKap Palladacycle
≥95%, solid
Synonym(s):
[Pd(μ-AcO)(4-Cl-CˆN-SO3Na)]2
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About This Item
Empirical Formula (Hill Notation):
C30H22Cl2N2Na2O10Pd2S2
CAS Number:
Molecular Weight:
964.36
UNSPSC Code:
12352101
NACRES:
NA.21
Product Name
SerrKap Palladacycle, ≥95%
SMILES string
[H]C(C1=C([Pd]23oc(C)o[Pd]4(C5=C(C([H])=[N]4C6=CC=C(S(=O)(O[Na])=O)C=C6)C=CC(Cl)=C5)oc(C)o2)C=C(Cl)C=C1)=[N]3C7=CC=C(S(=O)(O[Na])=O)C=C7
assay
≥95%
form
solid
greener alternative product characteristics
Catalysis
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color
yellow
greener alternative category
storage temp.
−20°C
Quality Level
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General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
SerrKap Palladacycle is a phosphine-free, water soluble Pd dimer catalyst used extensively for low temperature modifications of nucleosides via Suzuki-Miyaura and Heck reactions. It is also compatible with flow reaction conditions and suitable for late-stage oligonucleotide and DNA modification.
hcodes
pcodes
Hazard Classifications
Aquatic Chronic 4
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Santosh Kori et al.
Current protocols, 2(7), e502-e502 (2022-07-28)
Modification of nucleosides via cross-coupling processes has been carried out extensively on unprotected halonucleosides to produce functionalized nucleosides that are often developed for incorporation into oligonucleotides or used as fluorescent probes. This approach requires protection of the 5'-OH with the
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