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Merck
CN

940542

Lithium germanium phosphorus sulfide

(LGPS) solid electrolyte, powder

Synonym(s):

Sulfide solid electrolyte

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About This Item

Empirical Formula (Hill Notation):
GeLi10P2S12
CAS Number:
Molecular Weight:
588.78
UNSPSC Code:
12352302
NACRES:
NA.21
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grade

battery grade

Quality Level

description

application(s): battery manufacturing

Assay

99.9%

form

powder

mol wt

588.69 g/mol

composition

Li10GeP2S12

density

2.0 g/mL

application(s)

battery manufacturing

SMILES string

[Li].[S].[Ge].S=P([S-])([S-])[S-]

Related Categories

General description

Lithium germanium phosphorus sulfide solid electrolyte powder is a ceramic electrolyte with high ionic conductivity. Li10GeP2S12 (LGPS) is a white powder that crystallizes in the P42/nmc space group with three-dimensional interconnecting channels of Li+ ions that allow for fast Li+ diffusion. It belongs to the class of sulfide electrolytes and should be handled in a glovebox because LGPS is sensitive to air and moisture.

Application

Li10GeP2S12 (LGPS) is a solid electrolyte powder used in all-solid-state lithium batteries. It has an extremely high ionic conductivity of 12 mS cm–1 which is even higher than those of organic liquid electrolytes currently used in practical lithium-ion batteries. Typically, scientists pelletize (cold-press) the powder and may optionally anneal the pellet at high temperature (550 C) to enhance the ionic conductivity. LGPS is unstable against Li metal and is often used as the catholyte.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Elias Sebti et al.
Journal of the American Chemical Society, 144(13), 5795-5811 (2022-03-25)
In the pursuit of urgently needed, energy dense solid-state batteries for electric vehicle and portable electronics applications, halide solid electrolytes offer a promising path forward with exceptional compatibility against high-voltage oxide electrodes, tunable ionic conductivities, and facile processing. For this
Xiaona Li et al.
Journal of the American Chemical Society, 145(21), 11701-11709 (2023-05-17)
Inorganic solid-state electrolytes (SSEs) have gained significant attention for their potential use in high-energy solid-state batteries. However, there is a lack of understanding of the underlying mechanisms of fast ion conduction in SSEs. Here, we clarify the critical parameters that

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