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Merck
CN

943185

2,2-Difluoroethyl methyl carbonate

F2EMC, ≥99% (GC), anhydrous, battery grade

Synonym(s):

2,2-difluoroethyl methyl ester, Carbonic acid, DFM

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About This Item

Empirical Formula (Hill Notation):
C4H6F2O3
CAS Number:
Molecular Weight:
140.09
UNSPSC Code:
26111700
MDL number:
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grade

battery grade

Quality Level

assay

≥99% (GC)

form

liquid

dielectric constant

9.5

impurities

 μmol/L ≤ 5 µmol acid / g (eq. ≤ 100 ppm HF)

color

colorless to yellow

viscosity

2.1 cP

bp

75 °C (lit.)

application(s)

battery manufacturing

SMILES string

O=C(OC)OCC(F)F

InChI

1S/C4H6F2O3/c1-8-4(7)9-2-3(5)6/h3H,2H2,1H3

InChI key

QOARFWDBTJVWJG-UHFFFAOYSA-N

General description

F2EMC (di-fluoroethyl methyl carbonate) is a cutting-edge, partially fluorinated linear carbonate solvent engineered for advanced lithium‐ion battery electrolytes. Its unique molecular structure—featuring the –CHF group—optimizes Li⁺ ion solvation while promoting rapid ion conduction and maintaining ideal viscosity and oxidative stability. Our battery grade F2EMC is produced in an anhydrous state with ultra-low residual acid content, ensuring optimal performance when incorporated into electrolyte formulations.

Application

Our battery grade F2EMC is designed to unlock superior lithium‑ion battery performance by improving electrolyte stability and performance. Research suggests that incorporating F2EMC into battery electrolytes enhances fast-charging capability and reduces polarization by enabling efficient ion-transport. F2EMC forms a stable and uniform solid electrolyte interphase (SEI) on both graphite and silicon anode materials, lowering the cell′s charge transfer resistance. This results in extended cycle life and reliable high-voltage performance, making F2EMC an ideal choice for electric vehicles, portable electronics, and grid-scale energy storage applications.

Features and Benefits

• Low acid and trace water content: minimizes side reactions and corrosion, ensuring enhanced battery longevity.

• Partially fluorinated structure: optimizes Lisolvation and promotes efficient ion conduction for fast-charging and reliable performance.


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hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

No data available

flash_point_c

No data available

Regulatory Information

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Global Trade Item Number

SKUGTIN
943185-25G04065273019940
943185-100G04065273019933