94905
2-[Bis(2,4-di-tert-butyl-phenoxy)phosphinooxy]-3,5-di(tert-butyl)phenyl-palladium(II) chloride dimer
~12% Pd basis
Synonym(s):
Bedford Catalyst, Bis[2-(bis(2,4-di-tert-butylphenoxy)phosphino-κP-oxy)-3,5-di-tert-butylphenyl-κC]di-μ-chloro-dipalladium
Select a Size
About This Item
InChI
1S/2C42H62O3P.2Cl.2Pd/c2*1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18;;;;/h2*19-23,25-27H,1-18H3;;;;/q;;2*+1;2*-1
SMILES string
CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3c(cc(cc3C(C)(C)C)C(C)(C)C)[Pd-]4[Cl+][Pd-]([Cl+]4)c5cc(cc(c5OP(Oc6ccc(cc6C(C)(C)C)C(C)(C)C)Oc7ccc(cc7C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C
InChI key
HPRPCQXYHQYGHY-UHFFFAOYSA-N
form
crystals
reaction suitability
reagent type: catalyst
core: palladium
concentration
~12% Pd
Application
- Racemic and asymmetric sequential aldol condensations / addition reactions
- Miyaura borylations
- Lewis acid catalysis
- Allylation of aldehydes
- Addition reactions
- Alkoxy- and amidocarbonylations
Other Notes
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service