95352
(−)-Dibenzyl D-tartrate
≥98.0% (sum of enantiomers, HPLC)
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About This Item
Empirical Formula (Hill Notation):
C18H18O6
CAS Number:
Molecular Weight:
330.33
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4787873
Assay:
≥98.0% (sum of enantiomers, HPLC)
Form:
powder
InChI
1S/C18H18O6/c19-15(17(21)23-11-13-7-3-1-4-8-13)16(20)18(22)24-12-14-9-5-2-6-10-14/h1-10,15-16,19-20H,11-12H2/t15-,16-/m0/s1
SMILES string
O[C@@H]([C@H](O)C(=O)OCc1ccccc1)C(=O)OCc2ccccc2
InChI key
LCKIPSGLXMCAOF-HOTGVXAUSA-N
assay
≥98.0% (sum of enantiomers, HPLC)
form
powder
optical activity
[α]20/D −12.5±1°, c = 1.1% in acetone
mp
66-70 °C
functional group
ester, hydroxyl, phenyl
Quality Level
Related Categories
Application
(-)-Dibenzyl D-tartrate can be employed as a reactant to synthesize:
- 2,3-bis(8-Methoxyoctanoyl) dibenzyl tartrate (DBT) by reacting with 8-methoxyoctanoic acid in the presence of 1-ethyl-3-(3-(dimethylamino)propyl)carbodiimide (EDCI) as a coupling reagent.
- (-)-Chicoric acid (2,3-bis{[3-(3,4-dihydroxyphenyl)-1-oxoprop-2-enyl]oxy}butanedioic acid), as a potent inhibitor.
- Diesters of aziridine-2,3-dicarboxylic acid derivatives.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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A Convenient Synthesis of the Echinacea-Derived Immunostimulator and HIV-1 Integrase Inhibitor (-)-(2R, 3R)-Chicoric Acid
Lamidey A-M, et al.
Helvetica Chimica Acta, 85(8), 2328-2334 (2002)
An improved synthesis of aziridine-2, 3-dicarboxylates via azido alcohols?epimerization studies
Breuning A, et al.
Tetrahedron Asymmetry, 14(21), 3301-3312 (2003)
Allison Faig et al.
Biomacromolecules, 15(9), 3328-3337 (2014-07-30)
Amphiphilic macromolecules (AMs) composed of sugar backbones modified with branched aliphatic chains and a poly(ethylene glycol) (PEG) tail can inhibit macrophage uptake of oxidized low-density lipoproteins (oxLDL), a major event underlying atherosclerosis development. Previous studies indicate that AM hydrophobic domains
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