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Merck
CN

990445

Lithium manganese iron phosphate LMFP

greener alternative

Electrode sheet, aluminum substrate, size 5 in. x 10 in.

Synonym(s):

LMFP tape, Lithium iron manganese phosphate cathode

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About This Item

Linear Formula:
LiMn(x)Fe(x-1)PO4
UNSPSC Code:
26111700
NACRES:
NA.21
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Product Name

Lithium manganese iron phosphate (LMFP), Electrode sheet, aluminum substrate, size 5 in. x 10 in.

InChI key

ZWXLZABZHZXDGX-UHFFFAOYSA-K

SMILES string

[Li].[Mn].[Fe].O=P([O-])([O-])[O-]

grade

battery grade

description

3.8V vs. Li/Li+

form

sheet

composition

Active material loading 8.9 mg/cm2 ± 5%, ≥85% by wt (excluding current collector)

Quality Level

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

film size

80 μm × 16 μm , Al current collector

particle size

2 μm (active material characteristic)

capacity

(Areal capacity 1.25 mAh/cm2), (First discharge capacity ≥140 mAh/g)

application(s)

battery manufacturing

greener alternative category

General description

Our lithium manganese iron phosphate (LMFP) electrode sheet is a ready-to-use cathode designed for lithium-ion battery research. The LMFP cathode film is 80 µm thick, single-sided, and applied to a 16 µm thick aluminum foil current collector measuring 5 × 10 inches (127 mm × 254 mm). The composition consists of 88% lithium iron phosphate (LFP), 4% Poly(vinylidene fluoride) [PVDF], and 8% carbon black. The active material, olivine LiMnxFe1−xPO4, is a well-studied cathode material known for its excellent cycling stability.




Lithium Manganese Iron Phosphate is a sustainable cathode material combining manganese and iron for improved safety, cost-effectiveness, and environmental friendliness. Its use in lithium-ion batteries supports greener technologies by enhancing energy efficiency, extending battery life, and reducing reliance on scarce or toxic materials. Click here for more information.

Application

Our lithium manganese iron phosphate (LMFP) electrode serves as a cathode in lithium-ion battery research. It is cost-effective, environmentally friendly, and cobalt-free. Compared to lithium iron phosphate (LFP), LMFP boasts a nearly 20% higher energy density due to its higher nominal voltage (3.8 V for LMFP vs. 3.2 V for LFP). Moreover, LMFP offers high specific capacity (>150 mAh/g) and a longer cycle life compared to most other lithium-ion chemistries. LMFP cells experience a slower rate of capacity loss and greater calendar-life than other lithium-ion battery chemistries, such as layered oxides cathodes NMC and LCO. Due to its low cost, low toxicity, stability, and reliable performance, LMFP-based batteries are increasingly applied in vehicle and backup power applications.

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Jinli Liu et al.
Small (Weinheim an der Bergstrasse, Germany), 20(14), e2309629-e2309629 (2023-11-21)
LiMn1-yFeyPO4 (LMFP) is a significant and cost-effective cathode material for Li-ion batteries, with a higher working voltage than LiFePO4 (LFP) and improved safety features compared to layered oxide cathodes. However, its commercial application faces challenges due to a need for
Engineering the Transformation Strain in LiMnyFe1-yPO4 Olivines for Ultrahigh Rate Battery Cathodes
Ravnsb?k D B, et.al
Nano Letters, 16(4), 2375-2380 (2016)
Value of electrophysiologic testing in patients with previous myocardial infarction and nonsustained ventricular tachycardia. Philadelphia Arrhythmia Group
Kowey PR,et.al
The American Journal of Cardiology, 9, 594-598 (1990)

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