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H53704

N-Hydroxyphthalimide

Name: <I>N</I>-Hydroxyphthalimide
Brand: ALDRICH

97%, for peptide synthesis

Synonym(s):

2-Hydroxy-1H-isoindole-1,3(2H)-dione, 2-Hydroxyisoindole-1,3-dione, 2-Hydroxyphthalimide

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About This Item

Empirical Formula (Hill Notation):

C₈H₅NO₃

CAS Number:

524-38-9

Molecular Weight:

163.13

NACRES:

NA.22

PubChem Substance ID:

24895686

UNSPSC Code:

12352005

EC Number:

208-358-1

MDL number:

MFCD00005891

Beilstein/REAXYS Number:

131208

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Properties

Product Name

N-Hydroxyphthalimide, 97%

Quality Level

200

assay

97%

form

crystalline

reaction suitability

reaction type: Addition Reactions

mp

233 °C (dec.) (lit.)

application(s)

peptide synthesis

SMILES string

ON1C(=O)c2ccccc2C1=O

InChI

1S/C8H5NO3/c10-7-5-3-1-2-4-6(5)8(11)9(7)12/h1-4,12H

InChI key

CFMZSMGAMPBRBE-UHFFFAOYSA-N

Description

Application

For preparation of amine nucleosides for coupling into non-anionic, anti-sense oligonucleosides.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Tetrahedron Letters, 33, 2645-2645 (1992)

Metal-free, NHPI catalyzed oxidative cleavage of C-C double bond using molecular oxygen as oxidant.

Riyuan Lin et al.

Organic letters, 14(16), 4158-4161 (2012-08-03)

A metal-free N-hydroxyphthalimide (NHPI) catalyzed aerobic oxidative cleavage of olefins has been developed. Molecular oxygen is used as the oxidant and reagent for this oxygenation reaction. This methodology has prevented the use of toxic metals or overstoichiometric amounts of traditional

Oxidation of phenols by laccase and laccase-mediator systems.

Francesca D'Acunzo et al.

European journal of biochemistry, 269(21), 5330-5335 (2002-10-24)

To investigate how solubility and steric issues affect the laccase-catalysed oxidation of phenols, a series of oligomeric polyphenol compounds, having increasing size and decreasing solubility in water, was incubated with laccase. The extent of substrate conversion, and the nature of

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Global Trade Item Number

SKU	GTIN
H53704-500G	04061833553671
H53704-100G	04061833798126
H53704-5G	04061833327418