ALD00562
2,3-Dibromo-propylamine, hydrobromide
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About This Item
Empirical Formula (Hill Notation):
C3H8Br3N
CAS Number:
Molecular Weight:
297.81
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352200
MDL number:
InChI
1S/C3H7Br2N.BrH/c4-1-3(5)2-6;/h3H,1-2,6H2;1H
SMILES string
BrCC(Br)CN.[H]Br
InChI key
NQVQUJRBCVAMIL-UHFFFAOYSA-N
form
solid
reaction suitability
reaction type: C-C Bond Formation
Application
In tandem with Turbo Grignard (Aldrich product 656984) and an electrophilic trap, 2,3-Dibromo-propylamine hydrobromide generates a "spring loaded" electrophile, which is a convenient reagent for the installation of azetidine to secondary amines. This product is one of several synthetic useful reagents reported by Baran and coworkers on Strain-release amination.
Other Notes
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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