ALD00594
2-Hydroxynicotinaldehyde
97%
Synonym(s):
2-Hydroxy-pyridine-3-carbaldehyde, TDG4
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About This Item
Empirical Formula (Hill Notation):
C6H5NO2
CAS Number:
Molecular Weight:
123.11
NACRES:
NA.22
UNSPSC Code:
12352200
MDL number:
Assay:
97%
Form:
powder or crystals
InChI
1S/C6H5NO2/c8-4-5-2-1-3-7-6(5)9/h1-4H,(H,7,9)
InChI key
DNTYEVWEOFZXFE-UHFFFAOYSA-N
assay
97%
form
powder or crystals
reaction suitability
reaction type: C-C Bond Formation, reagent type: catalyst, reagent type: ligand
reaction type: C-H Activation
mp
223 °C
functional group
aldehyde
storage temp.
2-8°C
Application
This reagent was used as a catalytic transient directing group by Jin-Quan Yu′s lab for Pd(II)-catalyzed γ-C(sp3)-H arylation to couple free primary amines with aryl iodides. Reactions included Pd(OAc)2 683124 and low catalyst and directing group loading.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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