B22984
O-Benzylhydroxylamine hydrochloride
99%
Synonym(s):
Benzyloxyamine hydrochloride
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About This Item
Linear Formula:
C6H5CH2ONH2 · HCl
CAS Number:
Molecular Weight:
159.61
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-249-0
Beilstein/REAXYS Number:
3687991
MDL number:
Assay:
99%
Form:
crystals
Product Name
O-Benzylhydroxylamine hydrochloride, 99%
InChI key
HYDZPXNVHXJHBG-UHFFFAOYSA-N
InChI
1S/C7H9NO.ClH/c8-9-6-7-4-2-1-3-5-7;/h1-5H,6,8H2;1H
SMILES string
Cl.NOCc1ccccc1
assay
99%
form
crystals
mp
238 °C (subl.) (lit.)
Quality Level
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Related Categories
Application
Effective reagent used to prepare α-hydroxybenzylamines from α-hydroxyketones.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1
Storage Class
11 - Combustible Solids
wgk
WGK 3
ppe
Eyeshields, Gloves, type N95 (US)
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S M Breckenridge et al.
Journal of chromatography. B, Biomedical sciences and applications, 694(2), 289-296 (1997-07-04)
Extraction and derivatization of carbonyls to benzyloximes, pentafluorobenzyloximes or 2,4-dinitrophenylhydrazones is simplified and reaction times are substantially reduced by simultaneous sorption and derivatization from aqueous solution onto a solid phase. In this reaction a macroreticular polystyrene-divinylbenzene resin acts as a
A A Purmal et al.
Mutation research, 364(3), 193-207 (1996-12-02)
Duplex oligonucleotides containing the base lesion analogs, O-methylhydroxylamine- and O-benzylhydroxylamine-modified abasic (AP) sites, were substrates for the DNA N-glycosylases endonuclease III, formamidopyrimidine DNA N-glycosylase and T4 endonuclease V. These N-glycosylases are known to have associated AP lyase activities. In contrast
D F Magin
Journal of chromatography, 202(2), 255-261 (1980-12-19)
A qualitative and semi-quantitative method was established for the investigation of low-molecular-weight volatile carbonyl compounds in cigarette whole smoke. The carbonyls were trapped on a silica gel "column" and eluted with water. The aqueous solution was then treated with benzyloxyamine
Tetrahedron Letters, 32, 711-711 (1991)
G Cardillo et al.
Organic letters, 3(8), 1165-1167 (2001-05-12)
[reaction: see text]. The 1,4-addition of O-benzylhydroxylamine to alpha,beta-unsaturated imide 1 in the presence of BF3.Et2O proceeds with the preferential attack of the nucleophile on the Cbeta-re face. To explain this unexpected reactivity 1H, 13C, and 11B NMR investigations have
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