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B55203

(−)-Bornyl acetate

Name: (−)-Bornyl acetate
Brand: ALDRICH

95%

Synonym(s):

endo-(1S)-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl acetate

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About This Item

Empirical Formula (Hill Notation):

C₁₂H₂₀O₂

CAS Number:

5655-61-8

Molecular Weight:

196.29

UNSPSC Code:

12352108

NACRES:

NA.22

PubChem Substance ID:

329773262

EC Number:

227-101-4

Beilstein/REAXYS Number:

2502036

MDL number:

MFCD00867808

Assay:

95%

Form:

liquid

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Properties

vapor pressure

0.6 mmHg ( 20 °C)

Quality Level

100

assay

95%

form

liquid

optical activity

[α]20/D −38.10°, neat

refractive index

n20/D 1.463 (lit.)

bp

223-224 °C (lit.)

density

0.986 g/mL at 20 °C (lit.)

SMILES string

CC(=O)O[C@@H]1C[C@@H]2CC[C@@]1(C)C2(C)C

InChI

1S/C12H20O2/c1-8(13)14-10-7-9-5-6-12(10,4)11(9,2)3/h9-10H,5-7H2,1-4H3/t9-,10+,12+/m0/s1

InChI key

KGEKLUUHTZCSIP-HOSYDEDBSA-N

Description

Application

(−)-Bornyl acetate can be used:

As a key intermediate in the preparation of camphor.
To prepare (−)-englerin A, an anti-cancer agent.

Features and Benefits

Mimics the natural sex pheromone of the American cockroach.

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Storage Class

10 - Combustible liquids

flash_point_f

185.0 - 194.0 °F

flash_point_c

85 - 90 °C

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Bornyl acetate conversion enhancement by pervaporation in ionic liquid

Izak P, et al.

Planta Medica, 75(09), PI18-PI18 (2009)

Design and synthesis of terpene based englerin A mimics using chromium oxide mediated remote CH2 oxidation

Acerson MJ, et al.

Tetrahedron Letters, 56(23), 3277-3280 (2015)

Aldrichimica Acta, 16, 41-41 (1983)

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Global Trade Item Number

SKU	GTIN
B55203-100G	04061833433898
B55203-5G	04061833433904